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Characteristic
Features Of Silicone Rubber |
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1.
Heat
Resistance |
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Compared to organic
rubbers, silicone rubbers in general have incomparably high heat resistance.
Silicone rubbers can be used simi-permanently at 150C (302F) with
almost no change in the properties and can withstand more than 10,000
hours of continued service at 200C (392F).With this excellent heat
resistance, silicone rubbers are widely used in application requiring
excellent heat resistance.
Heat resistance of general
purpose silicone rubbers may differ considerably depending on the
formulation of the ingredients, selection of the curing agent, etc.
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2.
Cold
Resistance |
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Silicone rubbers have
excellent cold resistance. In contrast to brittle point of most organic, silicone
rubbers can
retain their elasticity, where most of other organic rubbers lose their
elasticity and become brittle. |
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3.
Weather ability |
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Silicone rubbers have excellent
weather ability. While rapid degradation is unavoidable in most organic
rubbers under the influence of ozone, produced by corona discharge, silicone
rubbers are virtually unaffected by ozone. Moreover, physical properties
of silicone rubbers are stable and little changed even by prolonged
exposure to ultraviolet light and over weathering conditions. |
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4.
Electrical
Properties |
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Silicone rubbers
have extremely high electrical resistance,10 14 to 10 16 ohm-cm, which
is stable over a wide range of temperatures and frequencies. The electrical
insulation of silicone rubbers is little affected by moisture and
immersion in water and therefore widely used as a material for electrical
insulation.
Silicone rubbers are highly resistant against corona discharge under
high voltage and arc discharge so that they also used as an electrical
insulating material under high voltage conditions. |
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5.
Electrical
Conductivity |
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Silicone rubbers can be
electro conductive by compounding with a filer such as carbon black. Several
grades of electroconductive silicone rubber are available.
Applications of electroconductive silicone rubbers include contact
points of keyboards, parts in electrical heater elements, parts in antistatic
devices, and shielding of high voltage cables. |
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6.
Radiation
Resistance |
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Although the radiation
resistance of diethyl silicone-based general-purpose silicone rubbers
is not particularly high compared to most organic rubbers, methyl phenyl
silicone rubbers ,formulated from a silicone gum having phenyl groups
introduced into the polymer molecules, have greatly improved radiation
resistance and are useful as a material for electrical insulation
of cables and connectors in atomic power plants.
Silicone rubbers can be used as a radiation-resistant material even
at high temperature as high as 200C (392F) to 300C (572F) , where
most organic rubbers such as mature rubber can no longer be used
due to thermal degradation.
Silicone rubber have a thermal conduct |
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7.
Thermal
Conductivity |
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vity of about 0.5 * 10-3
cal/cm-sec C. this value is higher than that of most organic rubbers.
Thermal conductivity property of silicone rubbers are used in heat-radiator
sheets, EMI gasket and heating rollers. |
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8.
Steam
Resistance
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Silicone rubbers absorb
a maximum of about 1% of water even after prolonged immersion in water. Mechanical
and electrical properties of silicone rubbers are little affected
by immersion irrespective of water temperature.
Although no degradation is seen in silicone rubbers in contact with
steam under normal pressure, pressurized steam may have considerable
influences on the properties of silicone rubbers. High pressure steam
at 150C (320F) or higher causes breakage of the polymeric main chain
of the organic polysiloxane so that the properties of the silicone
rubber are reduced. This problem can be solved by the improvement in
the formulation of the silicone rubber and selection of the proper
curing agent and post curing conditions. |
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9.
Chemical, Oil, and Solvent Resistance |
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Chemical, Oil, and Solvent
Resistance
At temperature below 100C (212F), the oil resistance of silicone rubber
is somewhat inferior to that of nitride and chloroprene rubbers. At temperature above 100C (212F), the oil resistance of silicone rubber
is superior to all types of organic rubber.
Silicone rubbers are chemical and solvent resistant as will. Polar organic
compounds such as aniline, alcohol, dilute alkaline and acid
solutions only slightly affect the properties of silicone rubber exhibiting
a maximum swelling of 10-15©‡.
Silicon rubber swells when contacted with moon-polar solvents such
as benzene, toluene,
and gasoline but he original properties are quickly restored when
the solvents are removed.
Silicone should not be used with highly concentrated strong acid and
alkaline solutions because they permanently damage silicone rubber.
Other solvents affect the properties of silicone rubber in different
ways so it is important to thoroughly test silicone rubber before
using in areas where solvents are being used. |
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10.
Compression
Set |
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Compression set is critical
when rubber is used as a packing material in pressure cookers and
other high pressure applications. The compression set of silicone rubber
is very low and varies little in temperature from -60C (76F) to 250C
(482F).On the other hand, organic rubbers are not suitable for use
as packing materials at this extreme temperature. |
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11.
Bending
Fatigue |
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Conventional rubbers
are generally not as resistant as organic rubbers against dynamic
stress such as fatigue by repeated bending.
Compounded rubbers which are 8 to 20 times as resistant against fatigue
by bending compared to conventional grades of silicone rubbers.
There silicone rubbers products are used in keyboards in office automation
instruments, rubber-made parts of transportation machines, and other
applications where repeating flexing and bending are required. |
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12.
High
Tear Strength |
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General purpose silicone
rubbers have a tear strength of about 15 kgf/cm. This relatively low
tear strength can be substantially increased by improving the chemical
structure of the organopolysiloxane and selecting the proper curing
agent and filler.
Several high-strength grades with a tear strength of 30-50 kgf/cm
are available and are widely used for molding intricately shaped, reverse-taper, and
large-sized articles.
Although silicone rubber generally has a lower strength than organic
rubber, at high temperature silicone rubber retains its strength whereas
organic rubber's strength gradually deteriorates. |
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13.
Gas
Permeability |
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Thin films of silicone
rubbers have somewhat larger permeability to gases and vapors than
organic rubber and plastic resin films. Relatively high selectivity
of permeability among different gases is also one of the characteristic
features of silicone rubber films. By virtue of these unique features, silicone
rubber films are promising as a membrane for the separation of gases
and liquids.
For example, heart-lung machines and oxygen enrichment are now being
developed using silicone rubber films as the gas exchange membrane. |
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14.
Vibration
Absorption |
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General purpose silicone
rubbers have a small loss factor so that they are not recommended
as a vibration-proof material. However, several vibration-proof silicone
products are available which serve as a vibration-proof material with
stability over a temperature range from -50C (-58F) to 100C (212F). |
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15.
Transparency
and Coloration |
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In contrast to most organic
rubbers colored in black due to the formulation of carbon black as
a reinforcing filler, silicone rubbers can be highly transparent when
the filler compounded for the reinforcement is a finely divided silica
filler which only slightly affects the transparency inherent in organopolysiloxane
gum.
Several high-transparency, high-strength silicone rubber products are
used to make various shaped articles such as tubes for and food-processing
machines.
High-transparency silicone rubber compounds can easily be colored by adding a pigment.
Vividly and brilliantly colored silicone rubber articles can be manufactured. |
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16.
Non-Stickiness
and Corrosion Resistance |
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Silicone rubbers are chemically
inert and as such are non corrosive to most metals and other materials. Silicone
rubbers also have excellent release properties making them ideal for
use as flexing rollers in copying machines, rollers in printing presses, sheets and
lost wax processes. |
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